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Materials Discovery, Synthesis & Characterisation

At the Functional Materials and Energy Devices (FMED) Lab, we specialize in the rational design, low-cost solution processing, and advanced characterisation of novel functional semiconductors and catalytic materials. Our work bridges fundamental materials physics with practical device implementation, focusing on scalable synthesis techniques and nanoscale property tuning to address global energy conversion and storage challenges.

Key Research Directions

Halide Perovskites and
Lead-Free Semiconductors

Halide Perovskites & Emerging Lead-Free Semiconductors

We investigate lead-halide perovskites, low-dimensional perovskites, and lead-free alternatives (such as bismuth/copper-based quaternary halides) for optoelectronic and energy applications. Our research addresses critical bottlenecks in operational stability, moisture tolerance, defect passivation, and environmental toxicity—paving the way for sustainable deployment in indoor photovoltaics, consumer electronics, and wireless IoT networks.

Nanostructured Oxides, 2D Materials & Molecular Complexes

Beyond traditional semiconductors, we synthesize and tune nanostructured metal oxides, 2D layered double hydroxides (LDHs), and molecular complexes (e.g., cobalt phthalocyanines). By controlling local coordination, stoichiometry, and heterojunction interfaces, we engineer these materials for high-performance electrocatalytic water splitting, green hydrogen generation, and CO₂ reduction.

Nanostructured
Oxides and 2D Materials
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Advanced Synchrotron & Spectroscopic Diagnostics

To unearth structure-property-function relationships, we leverage cutting-edge characterisation methods, including synchrotron-based techniques at the Diamond Light Source. Using methods such as Grazing-Incidence WideAngle X-ray Scattering (GIWAXS) and Hard X-ray Photoelectron Spectroscopy (HAXPES), we probe film morphology, buried interfaces, crystallographic orientation, and electronic surface states at atomic precision.

Fundamental Photophysics, Photodoping & Photon Recycling

We explore light-matter interactions and carrier transport dynamics across advanced semiconductor thin films. Our studies focus on passivating monovalent cation/halide additives (e.g., K⁺, Rb⁺), understanding photodoping mechanisms, controlling local charge-carrier accumulation, and harnessing photon recycling to maximize photoluminescence quantum efficiency and photovoltaic power conversion.

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Related Publications

01
Photodoping through local charge carrier accumulation in alloyed hybrid perovskites for highly efficient luminescence

S. Feldmann, M. Abdi-Jalebi, et al., R. H. Friend, F. Deschler. Nature Photonics, 14, 123–128 (2020).

02
Lanthanide-doped inorganic nanoparticles turn molecular triplet excitons bright

S. Han, M. Abdi-Jalebi, et al., A. Rao. Nature, 587, 594–599 (2020).

03
Photon recycling in lead iodide perovskite solar cells

L. M. Pazos-Outón, M. Abdi-Jalebi, et al., R. H. Friend, F. Deschler. Science, 351, 1430–1433 (2016).

04
Potassium- and Rubidium-Passivated Alloyed Perovskite Films: Optoelectronic Properties and Moisture Stability

M. Abdi-Jalebi, et al., R. H. Friend, S. D. Stranks. ACS Energy Letters, 3, 2671–2678 (2018)

05
Highly Absorbing Lead-Free Semiconductor Cu₂AgBiI₆ for Photovoltaic Applications from the Quaternary CuI–AgI–BiI₃ Phase Space

H. C. Sansom, M. Abdi-Jalebi, et al., L. M. Herz, H. J. Snaith, M. J. Rosseinsky. Journal of the American Chemical Society, 143 (10), 3983–3992 (2021)

06
Growth Engineering of CH₃NH₃PbI₃ Structures for High-Efficiency Solar Cells

M. I. Dar, M. Abdi-Jalebi, N. Arora, M. Grätzel, M. K. Nazeeruddin. Advanced Energy Materials, 6, 1501358 (2016).

07
Impact of Monovalent Cation Halide Additives on the Structural and Optoelectronic Properties of CH₃NH₃PbI₃ Perovskite

M. Abdi-Jalebi, et al., M. Grätzel, R. H. Friend. Advanced Energy Materials, 6, 1502472 (2016)

08
Recent progress in morphology optimization in perovskite solar cell

N. K. Tailor, M. Abdi-Jalebi, et al., S. Satapathi. Journal of Materials Chemistry A, 8, 21356–21386 (2020).

Key Research Directions

One of our primary research focuses is halide perovskites, a highly promising class of materials for next-generation high-performance optoelectronic devices, including solar cells and light-emitting diodes (LEDs). These materials challenge conventional understanding by exhibiting exceptional optoelectronic properties—such as strong light absorption and long charge-carrier diffusion lengths—despite having moderate defect densities. As a result, perovskite solar cells have achieved power conversion efficiencies (PCEs) exceeding 25%. While remarkable progress has been made over the past decade, the widespread adoption of perovskite-based energy technologies requires major advances in material stability, long-term operational lifetime, and environmental sustainability. Developing non-toxic alternatives is also essential for enabling applications in wireless sensor networks, consumer electronics, and Internet of Things (IoT) devices. Our research explores scalable synthesis methods for a wide range of halide perovskites and other advanced semiconductors. We investigate their structural and optoelectronic properties, including thin-film morphology, compositional engineering, charge-carrier dynamics, and photon recycling. In addition, we utilize advanced synchrotron characterization techniques at the Diamond Light Source, including Grazing-Incidence Wide-Angle X-ray Scattering (GIWAXS) and Hard X-ray Photoelectron Spectroscopy (HAXPES), to gain deeper insights into semiconductor materials and device performance.

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Representative Publications

[1] M Ibrahim Dar, Mojtaba Abdi‐Jalebi, Neha Arora, Michael Grätzel, Mohammad Khaja Nazeeruddin; “Growth Engineering of CH3NH3PbI3 Structures for High‐Efficiency Solar Cells” Adv. Energy Mater.  6, 1501358 (2016).

[2] Mojtaba Abdi-Jalebi, et al., Michael Grätzel, Richard H. Friend; “Impact of Monovalent Cation Halide Additives on the Structural and Optoelectronic Properties of CH3NH3PbI3 Perovskite” Adv. Energy Mater., 6, 1502472 (2016).

[3] Sanyang Han, et al., Mojtaba Abdi-Jalebi, Akshay Rao, “Lanthanide-doped inorganic nanoparticles turn molecular triplet excitons bright”, Nature, 587, 594–599 (2020).

[4] Naveen Kumar Tailor, Mojtaba Abdi-Jalebi, et al., Soumitra Satapathi, “Recent progress in morphology optimization in perovskite solar cell”, J. Mater. Chem. A, 2020,8, 21356-21386.

[5] Mojtaba Abdi-Jalebi, et al., Richard H. Friend, Samuel D. Stranks, “Potassium- and Rubidium-Passivated Alloyed Perovskite Films: Optoelectronic Properties and Moisture Stability”, ACS Energy Lett., 3, pp 2671–2678 (2018).

[6] Harry C Sansom, et al., Mojtaba Abdi-Jalebi, Laura M Herz, Henry J Snaith, Matthew J Rosseinsky, “Highly Absorbing Lead-Free Semiconductor Cu2AgBiI6 for Photovoltaic Applications from the Quaternary CuI–AgI–BiI3 Phase Space”, J. Am. Chem. Soc., 143, 10, 3983–3992 (2021).

[7] Sascha Feldmann, Mojtaba Abdi-Jalebi, et al., Felix Deschler, “Photodoping through local charge carrier accumulation in alloyed hybrid perovskites for highly efficient luminescence”, Nature Photonics, 14, 123–128 (2020).

[8] Luis Pazos-Outón, Mojtaba Abdi-Jalebi, et al., Richard Friend, Felix Deschler, “Photon recycling in lead iodide perovskite solar cells” Science, 351, 1430-1433 (2016).

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